-
Tytuł:
-
Synthesis and properties of a family of unsymmetric dinuclear complexes of Ln(III) (Ln = Eu, Gd, Tb).
-
Autorzy:
-
Aguilà D; Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain.
Barrios LA
Luis F
Repollés A
Roubeau O
Teat SJ
Aromí G
-
Źródło:
-
Inorganic chemistry [Inorg Chem] 2010 Aug 02; Vol. 49 (15), pp. 6784-6.
-
Typ publikacji:
-
Journal Article
-
Język:
-
English
-
Imprint Name(s):
-
Original Publication: [Easton, Pa.] American Chemical Society.
-
Entry Date(s):
-
Date Created: 20100708 Date Completed: 20101123 Latest Revision: 20100729
-
Update Code:
-
20240104
-
DOI:
-
10.1021/ic1008285
-
PMID:
-
20604562
-
A new ligand has been synthesized with the aim of favoring distinct coordination environments within lanthanide polynuclear complexes. It has led to the formation of three unsymmetrical [Ln(III)(2)] (Ln = Gd, Tb, Eu) complexes, exhibiting weak antiferromagnetic coupling and, for Eu and Tb, high single-ion magnetic anisotropy. All of these attributes are necessary for these clusters to behave as possible 2qubit quantum gates.