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Title of the item:

Structural modification strategies for the rational design of red/NIR region BODIPYs.

Title :
Structural modification strategies for the rational design of red/NIR region BODIPYs.
Authors :
Lu H; State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing, 210093, P. R. China. .
Mack J
Yang Y
Shen Z
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Source :
Chemical Society reviews [Chem Soc Rev] 2014 Jul 07; Vol. 43 (13), pp. 4778-823. Date of Electronic Publication: 2014 Apr 15.
Publication Type :
Journal Article; Research Support, Non-U.S. Gov't; Review
Language :
English
Imprint Name(s) :
Publication: Letchworth : Chemical Society
Original Publication: London, Chemical Society.
MeSH Terms :
Boron Compounds/*chemical synthesis
Spectroscopy, Near-Infrared/*methods
Boron Compounds/chemistry
Substance Nomenclature :
0 (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene)
0 (Boron Compounds)
Entry Date(s) :
Date Created: 20140416 Date Completed: 20150420 Latest Revision: 20140610
Update Code :
20210914
DOI :
10.1039/c4cs00030g
PMID :
24733589
Academic Journal
This review focuses on classifying different types of long wavelength absorbing BODIPY dyes based on the wide range of structural modification methods that have been adopted, and on tabulating their spectral and photophysical properties. The structure-property relationships are analyzed in depth with reference to molecular modeling calculations, so that the effectiveness of the different structural modification strategies for shifting the main BODIPY spectral bands to longer wavelengths can be readily compared, along with their effects on the fluorescence quantum yield (ΦF) values. This should facilitate the future rational design of red/NIR region BODIPY dyes for a wide range of different applications.

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