Direct oxidative lactonization of alkenoic acids mediated solely by NaIO4: beyond a simple oxidant.

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Tytuł:: Direct oxidative lactonization of alkenoic acids mediated solely by NaIO4: beyond a simple oxidant.
Autorzy:: Kang YB; Center of Advanced Nanocatalysis, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China. .
Chen XM
Yao CZ
Ning XS
Źródło:: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2016 May 04; Vol. 52 (36), pp. 6193-6. Date of Electronic Publication: 2016 Apr 14.
Typ publikacji:: Journal Article; Research Support, Non-U.S. Gov't
Język:: English
Imprint Name(s):: Original Publication: Cambridge : Royal Society of Chemistry
Entry Date(s):: Date Created: 20160415 Date Completed: 20170920 Latest Revision: 20170920
Update Code:: 20240104
DOI:: 10.1039/c6cc02246d
PMID:: 27078217
: Czasopismo naukowe

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Triflic acid-catalyzed direct oxidative lactonization of alkenoic acids mediated solely by NaIO4 without halogen salts is described. Sodium periodate works not only as an oxidant, but also as an active reagent and directly mediates the lactonization. A new cheap, green, and practical oxidative lactonization approach has been developed using NaIO4 as the sole reagent.

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