A fast and simple B-C bond formation in metallacarboranes avoiding halometallacarboranes and transition metal catalysts.

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Tytuł:: A fast and simple B-C bond formation in metallacarboranes avoiding halometallacarboranes and transition metal catalysts.
Autorzy:: Buades AB; Institut de Ciència de Materials de Barcelona - CSIC, Campus UAB, 08193, Bellaterra, Barcelona, Spain. .
Kelemen Z
Arderiu VS
Zaulet A
Viñas C
Teixidor F
Źródło:: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2020 Mar 21; Vol. 49 (11), pp. 3525-3531. Date of Electronic Publication: 2020 Feb 28.
Typ publikacji:: Journal Article
Język:: English
Imprint Name(s):: Original Publication: Cambridge, UK : Royal Society of Chemistry, c2003-
Entry Date(s):: Date Created: 20200229 Latest Revision: 20200317
Update Code:: 20240105
DOI:: 10.1039/c9dt04695j
PMID:: 32108183
: Czasopismo naukowe

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An electrophilic substitution on metallacarboranes by using a stabilized carbocation that can be made in situ is reported for the first time. This new synthetic methodology provides a new perspective on easy metallacarborane derivatization with organic fragments, which enhances the properties of both fragments and widens their possible applications.

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