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Tytuł pozycji:

Cobalt Nanoparticles-Catalyzed Widely Applicable Successive C-C Bond Cleavage in Alcohols to Access Esters.

Tytuł :
Cobalt Nanoparticles-Catalyzed Widely Applicable Successive C-C Bond Cleavage in Alcohols to Access Esters.
Autorzy :
Luo H; Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.; University of Chinese Academy of Sciences, Beijing, 100049, China.
Wang L; Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
Shang S; Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
Li G; Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
Lv Y; Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
Gao S; Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
Dai W; Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
Pokaż więcej
Źródło :
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2020 Oct 19; Vol. 59 (43), pp. 19268-19274. Date of Electronic Publication: 2020 Aug 24.
Typ publikacji :
Journal Article
Język :
English
Imprint Name(s) :
Publication: <2004-> : Weinheim : Wiley-VCH
Original Publication: Weinheim/Bergstr. : New York, : Verlag Chemie ; Academic Press, c1962-
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Grant Information :
No. 21773227, 21773232, and 21902151 National Natural Science Foundation of China
Contributed Indexing :
Keywords: C−C bond; aerobic oxidative cleavage; alcohols; esters; heterogeneous cobalt catalyst
Entry Date(s) :
Date Created: 20200715 Latest Revision: 20201207
Update Code :
20210301
DOI :
10.1002/anie.202008261
PMID :
32662588
Czasopismo naukowe
Selective cleavage and functionalization of C-C bonds have important applications in organic synthesis and biomass utilization. However, functionalization of C-C bonds by controlled cleavage remains difficult and challenging because they are inert. Herein, we describe an unprecedented efficient protocol for the breaking of successive C-C bonds in alcohols to form esters with one or multiple carbon atoms less using heterogeneous cobalt nanoparticles as catalyst with dioxygen as the oxidant. A wide range of alcohols including inactive long-chain alkyl aryl alcohols undergo smoothly successive cleavage of adjacent -(C-C) n - bonds to afford the corresponding esters. The catalyst was used for seven times without any decrease in activity. Characterization and control experiments disclose that cobalt nanoparticles are responsible for the successive cleavage of C-C bonds to achieve excellent catalytic activity, while the presence of Co-N x has just the opposite effect. Preliminary mechanistic studies reveal that a tandem sequence reaction is involved in this process.
(© 2020 Wiley-VCH GmbH.)

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