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Tytuł:
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Hydrogen production in two-chamber MEC using a low-cost and biodegradable poly(vinyl) alcohol/chitosan membrane.
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Autorzy:
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González-Pabón MJ; Laboratory of Biosensors and Bioanalysis (LABB), Biochemistry Department and IQUIBICEN-CONICET, Science School, University of Buenos Aires, Buenos Aires, Argentina; Laboratory for Research on Advanced Processes for Water Treatment, Instituto de Ingeniería, Unidad Académica Juriquilla, Universidad Nacional Autónoma de México, Blvd. Juriquilla 3001, 76230 Santiago de Queretaro, Queretaro, Mexico.
Cardeña R; Laboratory for Research on Advanced Processes for Water Treatment, Instituto de Ingeniería, Unidad Académica Juriquilla, Universidad Nacional Autónoma de México, Blvd. Juriquilla 3001, 76230 Santiago de Queretaro, Queretaro, Mexico.
Cortón E; Laboratory of Biosensors and Bioanalysis (LABB), Biochemistry Department and IQUIBICEN-CONICET, Science School, University of Buenos Aires, Buenos Aires, Argentina.
Buitrón G; Laboratory for Research on Advanced Processes for Water Treatment, Instituto de Ingeniería, Unidad Académica Juriquilla, Universidad Nacional Autónoma de México, Blvd. Juriquilla 3001, 76230 Santiago de Queretaro, Queretaro, Mexico. Electronic address: .
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Źródło:
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Bioresource technology [Bioresour Technol] 2021 Jan; Vol. 319, pp. 124168. Date of Electronic Publication: 2020 Sep 23.
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Typ publikacji:
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Journal Article
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Język:
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English
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Imprint Name(s):
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Original Publication: Barking, Essex, England : New York, N.Y. : Elsevier Applied Science ; Elsevier Science Pub. Co., 1991-
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MeSH Terms:
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Chitosan*
Electrolysis ; Hydrogen ; Polyvinyl Alcohol ; Polyvinyl Chloride
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Contributed Indexing:
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Keywords: Chitosan; Hydrogen; Membrane; Microbial electrolysis cell; Nafion; Polyvinyl alcohol
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Substance Nomenclature:
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7YNJ3PO35Z (Hydrogen)
9002-86-2 (Polyvinyl Chloride)
9002-89-5 (Polyvinyl Alcohol)
9012-76-4 (Chitosan)
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Entry Date(s):
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Date Created: 20200929 Date Completed: 20201125 Latest Revision: 20201125
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Update Code:
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20240105
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DOI:
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10.1016/j.biortech.2020.124168
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PMID:
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32992275
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Hydrogen production was evaluated in two-chamber microbial electrolysis cells (MEC), where the chambers of the cell were separated using a new economical and environmentally friendly membrane made of poly (vinyl) alcohol/chitosan (PVA/CS). The MEC performance was compared to that of Nafion. The obtained results indicated that the MEC performance for hydrogen production did not show significant differences between the PVA/CS and Nafion membranes. MEC with PVA/CS showed the hydrogen production rate and hydrogen yield of 1277 ± 46 mL H 2 L cat -1 d -1 and 974 ± 116 mL H 2 g acetate -1 , respectively. The PVA/CS membrane allowed acetate removal that was 7% higher than that of Nafion due to the lower pH gradient and a lower voltage drop that increased the ion transfer across the membrane.
(Copyright © 2020 Elsevier Ltd. All rights reserved.)