Small Molecule Activation by Two-Coordinate Acyclic Silylenes.

Tytuł:: Small Molecule Activation by Two-Coordinate Acyclic Silylenes.
Autorzy:: Fujimori S; Department of Chemistry WACKER-Institute of Silicon Chemistry and Catalysis Research Center Technische Universität München Lichtenbergstraße 4 85748 Garching bei München Germany.
Inoue S; Department of Chemistry WACKER-Institute of Silicon Chemistry and Catalysis Research Center Technische Universität München Lichtenbergstraße 4 85748 Garching bei München Germany.
Źródło:: European journal of inorganic chemistry [Eur J Inorg Chem] 2020 Sep 07; Vol. 2020 (33), pp. 3131-3142. Date of Electronic Publication: 2020 Jul 28.
Typ publikacji:: Journal Article; Review
Język:: English
Imprint Name(s):: Original Publication: Weinheim, Germany : Wiley-VCH, c1998-
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Contributed Indexing:: Keywords: Acyclic compounds; Reaction mechanisms; Silicon; Silylenes; Small molecule activation
Entry Date(s):: Date Created: 20201001 Latest Revision: 20231104
Update Code:: 20240105
PubMed Central ID:: PMC7507849
DOI:: 10.1002/ejic.202000479
PMID:: 32999589
: Czasopismo naukowe

Pełny tekst

In recent decades, the chemistry of stable silylenes (R 2 Si:) has evolved significantly. The first major development in this chemistry was the isolation of a silicocene which is stabilized by the Cp* (Cp* = η 5 -C 5 Me 5 ) ligand in 1986 and subsequently the isolation of a first N -heterocyclic silylene (NHSi:) in 1994. Since the groundbreaking discoveries, a large number of isolable cyclic silylenes and higher coordinated silylenes, i.e. Si(II) compounds with coordination number greater than two, have been prepared and the properties investigated. However, the first isolable two-coordinate acyclic silylene was finally reported in 2012. The achievements in the synthesis of acyclic silylenes have allowed for the utilization of silylenes in small molecule activation including inert H 2 activation, a process previously exclusive to transition metals. This minireview highlights the developments in silylene chemistry, specifically two-coordinate acyclic silylenes, including experimental and computational studies which investigate the extremely high reactivity of the acyclic silylenes.
(© 2020 The Authors. Published by Wiley‐VCH Verlag GmbH & Co. KGaA.)

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