<superscript>57</superscript> Fe Mössbauer Spectroscopy as a Tool for Study of Spin States and Magnetic Interactions in Inorganic Chemistry. - OpacWWW

Tytuł:: Fe Mössbauer Spectroscopy as a Tool for Study of Spin States and Magnetic Interactions in Inorganic Chemistry.
Autorzy:: Kuzmann E; Laboratory of Nuclear Chemistry, Institute of Chemistry, Eötvös Loránd University, 1117 Budapest, Hungary.
Homonnay Z; Laboratory of Nuclear Chemistry, Institute of Chemistry, Eötvös Loránd University, 1117 Budapest, Hungary.
Klencsár Z; Laboratory of Nuclear Chemistry, Institute of Chemistry, Eötvös Loránd University, 1117 Budapest, Hungary.; Center for Energy Research, 1121 Budapest, Hungary.
Szalay R; Laboratory of Nuclear Chemistry, Institute of Chemistry, Eötvös Loránd University, 1117 Budapest, Hungary.
Źródło:: Molecules (Basel, Switzerland) [Molecules] 2021 Feb 18; Vol. 26 (4). Date of Electronic Publication: 2021 Feb 18.
Typ publikacji:: Journal Article; Review
Język:: English
Imprint Name(s):: Original Publication: Basel, Switzerland : MDPI, c1995-
MeSH Terms:: Chemistry, Inorganic*
Magnetic Phenomena*
Spectroscopy, Mossbauer*
Spin Labels*
Models, Molecular ; Molecular Conformation
References:: Nat Chem. 2013 Jul;5(7):577-81. (PMID: 23787747)
Inorg Chem. 2009 Oct 5;48(19):9345-55. (PMID: 19711941)
J Am Chem Soc. 2009 Sep 9;131(35):12693-702. (PMID: 19670870)
J Am Chem Soc. 2009 Jan 21;131(2):404-5. (PMID: 19113855)
J Am Chem Soc. 2004 Aug 25;126(33):10206-7. (PMID: 15315408)
Nat Mater. 2008 Mar;7(3):179-86. (PMID: 18297126)
J Am Chem Soc. 2002 Jul 17;124(28):8416-27. (PMID: 12105923)
Nature. 2001 Apr 12;410(6830):789-93. (PMID: 11298441)
ACS Omega. 2019 Mar 08;4(3):5076-5082. (PMID: 31459685)
Contributed Indexing:: Keywords: Mössbauer spectroscopy; iron(II/III) phthalocyanines; magnetic exchange interactions; molecular magnetism; spin crossover
Substance Nomenclature:: 0 (Spin Labels)
Entry Date(s):: Date Created: 20210306 Date Completed: 20210408 Latest Revision: 20210408
Update Code:: 20240104
PubMed Central ID:: PMC7922376
DOI:: 10.3390/molecules26041062
PMID:: 33670484
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Pełny tekst

In this mini-review of our research group's activity, the application of 57 Fe Mössbauer spectroscopy in studies of electronic structure, coordination environment, and magnetic interactions in an interesting series of Fe(II/III) compounds selected is discussed. We selected two prominent phenomena that arose during investigations of selected groups of compounds carried out at different periods of time: (1) very high magnetic hyperfine fields observed at low temperatures; (2) changes in the oxidation state of the central iron atom of complexes in the solid state during interactions with gaseous O 2 /H 2 O mixtures, resulting in spin crossover (SCO).

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57 Fe Mössbauer Spectroscopy as a Tool for Study of Spin States and Magnetic Interactions in Inorganic Chemistry.