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Tytuł:
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Composite TiO 2 -based photocatalyst with enhanced performance.
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Autorzy:
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Muzikova B; Center for Innovation in the field of Nanomaterials and Nanotechnologies, J. Heyrovsky Institute of Physical Chemistry of the CAS, Dolejskova 3, Prague, 18223, Czech Republic.; Forensic Laboratory of Biologically Active Substances, Department of Chemistry of Natural Compounds, University of Chemistry and Technology Prague, Technicka 3, 16628, Prague, Czech Republic.
Martiniakova I; Center for Innovation in the field of Nanomaterials and Nanotechnologies, J. Heyrovsky Institute of Physical Chemistry of the CAS, Dolejskova 3, Prague, 18223, Czech Republic.; Department of Physical Chemistry, University of Chemistry and Technology Prague, Technicka 5, Prague, 16628, Czech Republic.
Mikyskova E; Center for Innovation in the field of Nanomaterials and Nanotechnologies, J. Heyrovsky Institute of Physical Chemistry of the CAS, Dolejskova 3, Prague, 18223, Czech Republic.
Mergl M; Department of Low-Dimensional Systems, J. Heyrovsky Institute of Physical Chemistry of the CAS, Dolejskova 3, Prague, 18223, Czech Republic.
Kalbac M; Department of Low-Dimensional Systems, J. Heyrovsky Institute of Physical Chemistry of the CAS, Dolejskova 3, Prague, 18223, Czech Republic.
Zouzelka R; Center for Innovation in the field of Nanomaterials and Nanotechnologies, J. Heyrovsky Institute of Physical Chemistry of the CAS, Dolejskova 3, Prague, 18223, Czech Republic.
Rathousky J; Center for Innovation in the field of Nanomaterials and Nanotechnologies, J. Heyrovsky Institute of Physical Chemistry of the CAS, Dolejskova 3, Prague, 18223, Czech Republic. .
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Źródło:
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Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology [Photochem Photobiol Sci] 2023 Jan; Vol. 22 (1), pp. 73-86. Date of Electronic Publication: 2022 Sep 24.
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Typ publikacji:
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Journal Article
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Język:
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English
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Imprint Name(s):
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Publication: 2021- : [London] : Springer
Original Publication: Cambridge, UK : Royal Society of Chemistry, c2002-
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MeSH Terms:
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Titanium*/chemistry
Oxides*
Catalysis
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References:
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Grant Information:
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19-12109S Grantová Agentura České Republiky; 19-21801S Grantová Agentura České Republiky; LM2018124 Ministerstvo Školství, Mládeže a Tělovýchovy; CZ.02.1.01/0.0/0.0/16_013/0001821 Ministerstvo Školství, Mládeže a Tělovýchovy; MSM200402101 Akademie Věd České Republiky; Strategy AV21 No. 23 Akademie Věd České Republiky; FV40209 Ministerstvo Průmyslu a Obchodu
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Contributed Indexing:
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Keywords: Air purification; Composite photocatalyst; Metal oxides; NOx; Photocatalysis; Titanium dioxide
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Substance Nomenclature:
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15FIX9V2JP (titanium dioxide)
D1JT611TNE (Titanium)
0 (Oxides)
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Entry Date(s):
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Date Created: 20220924 Date Completed: 20230111 Latest Revision: 20230111
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Update Code:
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20240104
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DOI:
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10.1007/s43630-022-00300-5
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PMID:
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36152273
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TiO 2 is the most studied photocatalyst because of its non-toxicity, chemical stability, and low cost. However, the problem of TiO 2 is its low activity in the visible region of the spectrum. In this study, we focused on the preparation of composite photocatalytic materials with altered light absorption properties. TiO 2 P25 and various metal oxides were mechanically joined by ball-milling and immobilized on glass plates. The prepared samples were evaluated based on their ability to degrade NO in gas phase. The formation of undesirable byproducts was also investigated. Four best performing composites were later chosen, characterized, and further evaluated under various conditions. According to their performance, the metal oxide additives can be divided into three groups. P25/Fe 2 O 3 showed the most promising results-an increase in overall deNO x activity under modified ISO conditions and altered selectivity (less NO 2 is formed) under both simulated outdoor and simulated indoor conditions. On the other hand, P25/V 2 O 5 composite showed negligible photocatalytic activity. The intermediate group includes P25/WO 3 and P25/ZnO photocatalysts, whose performances are similar to those of pristine P25.
(© 2022. The Author(s), under exclusive licence to European Photochemistry Association, European Society for Photobiology.)