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Tytuł:
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Substrate‐Independent Magnetic Bistability in Monolayers of the Single‐Molecule Magnet Dy2 on Metals and Insulators.
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Autorzy:
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Krylov, Denis S.
Schimmel, Sebastian
Dubrovin, Vasilii
Liu, Fupin
Nguyen, T. T. Nhung
Spree, Lukas
Chen, Chia‐Hsiang
Velkos, Georgios
Bulbucan, Claudiu
Westerström, Rasmus
Studniarek, Michał
Dreiser, Jan
Hess, Christian
Büchner, Bernd
Avdoshenko, Stanislav M.
Popov, Alexey A.
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Temat:
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FULLERENES
TRANSITION metals
MONOMOLECULAR films
MAGNETIC hysteresis
FARADAY effect
MAGNETS
ELECTRONIC structure
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Źródło:
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Angewandte Chemie; 3/27/2020, Vol. 132 Issue 14, p5805-5813, 9p
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Magnetic hysteresis is demonstrated for monolayers of the single‐molecule magnet (SMM) Dy2ScN@C80 deposited on Au(111), Ag(100), and MgO|Ag(100) surfaces by vacuum sublimation. The topography and electronic structure of Dy2ScN@C80 adsorbed on Au(111) were studied by STM. X‐ray magnetic CD studies show that the Dy2ScN@C80 monolayers exhibit similarly broad magnetic hysteresis independent on the substrate used, but the orientation of the Dy2ScN cluster depends strongly on the surface. DFT calculations show that the extent of the electronic interaction of the fullerene molecules with the surface is increasing dramatically from MgO to Au(111) and Ag(100). However, the charge redistribution at the fullerene‐surface interface is fully absorbed by the carbon cage, leaving the state of the endohedral cluster intact. This Faraday cage effect of the fullerene preserves the magnetic bistability of fullerene‐SMMs on conducting substrates and facilitates their application in molecular spintronics. [ABSTRACT FROM AUTHOR]
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