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Tytuł pozycji:

Absolute configuration of seco‐eudesmanolide inuloxin D from experimental and predicted chiroptical studies of its 4‐O‐acetyl derivative.

Tytuł :
Absolute configuration of seco‐eudesmanolide inuloxin D from experimental and predicted chiroptical studies of its 4‐O‐acetyl derivative.
Autorzy :
Johnson, Jordan L.
Santoro, Ernesto
Zatout, Roukia
Petrovic, Ana G.
Cimmino, Alessio
Superchi, Stefano
Evidente, Antonio
Berova, Nina D.
Polavarapu, Prasad L.
Pokaż więcej
Temat :
PARASITIC plants
VIBRATIONAL circular dichroism
PLANT extracts
DODDER
BROOMRAPES
Źródło :
Chirality; May2021, Vol. 33 Issue 5, p233-241, 9p
Czasopismo naukowe
Sesquitepenoids inuloxins A–D, belonging to different subgroups, were isolated from Dittrichia viscosa and showed potential biocontrol of some parasitic plants as Pelipanche, Orobanche, and Cuscuta species. The absolute configurations of the first three inuloxins A–C were previously determined by using experimental and computational chiroptical spectroscopic methods. The absolute configuration of inuloxin D remains to be established. The bioactive inuloxin E, closely related to inuloxin D, was recently isolated from the same plant organic extract. The same relative configuration of inuloxin D was assigned to inuloxin E by comparison of their NMR spectroscopic data. The absolute configurations of inuloxin D and inuloxin E are suggested in this work by analysis of the experimental and predicted chiroptical properties of the 4‐O‐acetyl derivative of inuloxin D. [ABSTRACT FROM AUTHOR]
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