Organic‐Inorganic Superlattices of Vanadium Oxide@Polyaniline for High‐Performance Magnesium‐Ion Batteries.

Rechargeable magnesium batteries (RMBs) have attracted significant attention owing to the high energy density and economic viability. However, the lack of suitable cathode materials, owing to the high polarizability of divalent Mg‐ion and slow Mg‐ion diffusion, hinders the development of RMBs. V2O5 is a promising RMBs cathode material, but its limited interlayer spacing is unfavorable for the rapid diffusion of Mg2+, demonstrating unsatisfactory electrochemical performance. In this study, the superlattices of V2O5 and polyaniline (PANI) with expanded interlayer spacing are assembled as the cathode material for RMBs. The intercalation of PANI in the interlayer region of V2O5 significantly improves the reversible capacities, Mg2+ diffusion kinetics, and cycling performance of the PVO cathode. Furthermore, RMBs with PVO as the cathode and Mg metal as the anode deliver high specific capacities. The introduced polyaniline layer not only expands the interlayer spacing of V2O5, but also increases the electrical conductivity. Moreover, ex situ XRD characterization indicates that PVO does not undergo obvious phase transformation with the continuous insertion of Mg2+, which may be ascribed to the π‐conjugated chains of PANI that give flexibility to the structure to improve cycling stability. This study demonstrates that designing organic‐inorganic superlattices is an efficient strategy for developing high‐performance cathode materials for RMBs. [ABSTRACT FROM AUTHOR]
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