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Tytuł:
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Synthesis of End-capped Regioregular Poly(3-hexylthiophene)s via Direct Arylation.
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Autorzy:
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Wang, Qifeng
Wakioka, Masayuki
Ozawa, Fumiyuki
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Źródło:
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Macromolecular Rapid Communications; Jul2012, Vol. 33 Issue 14, p1203-1207, 5p
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The synthesis of regioregular head-to-tail poly(3-hexylthiophene)s capped with aryl groups (Ar-HT-P3HTs) has been accomplished by palladium-catalyzed polycondensation of 2-bromo-3-hexylthiophene ( 1) via direct arylation. A variety of aryl groups are installed at the initiated end in 86%-98% selectivity using aryl bromides and iodides as capping agents. The polymerization proceeds via a two-stage process. Before monomer 1 is consumed, the competitive formation of end-capped and non-capped HT-P3HTs is operative, where the molecular weight increases linearly with monomer conversion. After 1 is consumed, the resulting polymers are coupled with each other to afford highly end-capped HT-P3HTs. [ABSTRACT FROM AUTHOR]
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