Transition metal complexes with thiosemicarbazide-based ligands. Part 60. Reactions of copper(II) bromide with pyridoxal S-methylisothiosemicarbazone (PLITSC). Crystal structure of [Cu(PLITSC−H)H2O]Br•H2O

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Tytuł:: Transition metal complexes with thiosemicarbazide-based ligands. Part 60. Reactions of copper(II) bromide with pyridoxal S-methylisothiosemicarbazone (PLITSC). Crystal structure of [Cu(PLITSC−H)H2O]Br•H2O
Autorzy:: Leovac Vukadin M.
Vojinović-Ješić Ljiljana S.
Ivković Sonja A.
Rodić Marko V.
Jovanović Ljiljana S.
Holló Berta
Mészáros-Szécsényi Katalin
Temat:: copper(II) complexes
pyridoxal S-methylisothiosemicarbazone
crystal structure
spectra
thermal analysis
Chemistry
QD1-999
Źródło:: Journal of the Serbian Chemical Society, Vol 79, Iss 3, Pp 291-302 (2014)
Wydawca:: Serbian Chemical Society, 2014.
Rok publikacji:: 2014
Kolekcja:: LCC:Chemistry
Typ dokumentu:: article
Opis pliku:: electronic resource
Język:: English
ISSN:: 0352-5139
1820-7421
Relacje:: https://doaj.org/toc/0352-5139; https://doaj.org/toc/1820-7421
DOI:: 10.2298/JSC130622084L
Dostęp URL:: https://doaj.org/article/2f647c5f1b4548d58620c5af728d098d Link otwiera się w nowym oknie
Numer akcesji:: edsdoj.2f647c5f1b4548d58620c5af728d098d
: Czasopismo naukowe

Pełny tekst

The synthesis and structural characterization of a square-planar copper(II) complex with pyridoxal S-methylisothiosemicarbazone (PLITSC) of the formula [Cu(PLITSC−H)H2O]Br•H2O (1) as the first Cu(II) complex with monoanionic form of this ligand were described. Complex 1 together with two previously synthesized complexes [Cu(PLITSC)Br2] (2) and [Cu(PLITSC)Br(MeOH)]Br (3) were characterized by elemental analysis, IR and electronic spectra and also by the methods of thermal analysis, conductometry and magnetochemistry. [Projekat Pokrajisnkog sekretarijata za nauku i tehnoloski razvoj Vojvodine i Ministarstva nauke Republike Srbije, br. 172014]

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