H-cluster assembly intermediates built on HydF by the radical SAM enzymes HydE and HydG.
Autorzy:
Byer AS; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT, 59717, USA. Shepard EM; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT, 59717, USA. Ratzloff MW; Biosciences Center, National Renewable Energy Laboratory, Golden, CO, 80401, USA. Betz JN; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT, 59717, USA. King PW; Biosciences Center, National Renewable Energy Laboratory, Golden, CO, 80401, USA. BroderickWE; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT, 59717, USA. Broderick JB; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT, 59717, USA. .
Radical SAM enzymes: surprises along the path to understanding mechanism.
Autorzy:
BroderickWE; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT, 59717, USA. Broderick JB; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT, 59717, USA. .
Radical SAM catalysis via an organometallic intermediate with an Fe-[5'-C]-deoxyadenosyl bond.
Autorzy:
Horitani M; Department of Chemistry, Northwestern University, Evanston, IL 60208, USA. Shisler K; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, USA. BroderickWE; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, USA. Hutcheson RU; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, USA. Duschene KS; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, USA. Marts AR; Department of Chemistry, Northwestern University, Evanston, IL 60208, USA. Hoffman BM; Department of Chemistry, Northwestern University, Evanston, IL 60208, USA. . Broderick JB; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, USA. .
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Źródło:
Science (New York, N.Y.) [Science] 2016 May 13; Vol. 352 (6287), pp. 822-5. Date of Electronic Publication: 2016 May 12.
Typ publikacji:
Journal Article; Research Support, N.I.H., Extramural
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